Vicinal dichlorine elimination at dichloroalkenes promoted by a well-defined iron(0) complex.
نویسندگان
چکیده
Dechlorination reactions at sp(2) C-Cl bonds by a pentaphosphino zero-valent iron (ZVI) complex are proposed to follow an oxidative addition, β-Cl-elimination pathway en route to iron-chloride, iron-hydride and iron-acetylide products, the distribution being dependent on the nature of alkyne produced.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 40 8 شماره
صفحات -
تاریخ انتشار 2011